Factors Affecting the Performance of Refractory Castables

There are many varieties of refractory castables, with different mix proportions, different performances, different construction methods, and different maintenance systems. Rongsheng Refractory Material Factory has found that there are many factors that affect the performance of refractory castables based on their production and sales experience over the years. The specific ones are as follows.

Application Fields of Refractory Castables
Application Fields of Refractory Castables
  1. Amount of cement

Cement is one of the important components of refractory castables. It is an important material that determines strength and also affects other properties. Different types of cement and their dosage have different effects on performance. For example, CA-50 cement high-alumina refractory castables, refractory aggregates and powders are both secondary alumina clinker, and the amount of water added is 10%. With the increase of cement dosage, the compressive strength at room temperature will increase. The compressive strength after burning at 1200℃ is 40%~65% lower than the drying compressive strength. The refractoriness and load softening temperature continue to decrease, and the linear shrinkage after burning also increases. This is because CA-50 cement has a high impurity content and low refractoriness. When the dosage increases, the amount of liquid phase in the heating process of the castable is large, resulting in a decrease in performance. Therefore, under the condition of ensuring the strength at room temperature, the amount of CA-50 cement should be minimized to improve the high-temperature performance of the refractory castable. When the amount of cement is reduced, the refractory powder should be appropriately increased so that the combined amount of cement and powder can fully wrap the refractory aggregate and the refractory castable can achieve the maximum density. The commonly used cement dosage is 10%~15%.

  1. Water addition

Different types of aluminate cement can produce different refractory castables. The same type of cement can also be used to make multiple types of refractory castables. When the mix ratio and process conditions of refractory castables are the same, the influence of water dosage on the performance of refractory castables is basically the same. Taking CA-50 cement high-alumina refractory castable as an example, the influence of water dosage on the performance of castables is that refractory aggregate and powder are both secondary alumina clinker, aggregate is 70% of the total material <15mm, powder and cement are 15% each. After the initial setting of the molding, the mold is removed after wet curing for 1d, and then standard curing is carried out for 2d to test various properties. As the amount of water used in the castable increases, various properties generally decrease significantly. The compressive strength at room temperature decreases by 27%~35%, the drying compressive strength decreases to 19.1MPa, the compressive strength after burning decreases by about 40%, and the high temperature compressive strength decreases by about 57%. The load softening temperature dropped from 1400℃ to 1250℃, and the post-firing line change dropped from -0.38% to -0.96%. The apparent porosity increased from 19% to 23%, and the bulk density dropped from 2.29g/cm3 to 2.17g/cm3. That is to say, the selection of water dosage (or water-cement ratio) is very important when preparing aluminate cement refractory castables. When the amount of water is large, after heating, the water escapes, the pores increase, the structure becomes loose, and various properties are reduced comprehensively. Therefore, under the condition of ensuring its construction and workability, the amount of water in the mixture should be minimized. Under the premise of not adding water reducing agent, the appropriate water dosage of aluminate cement refractory castable is 10%~13%.

It should be pointed out that when the mix ratio and production process of refractory castables are basically the same, there is an optimal value for its water dosage. Therefore, when constructing and making aluminate cement refractory castables, they should be tried and mixed first to select the best fluidity. Compare the strength at room temperature and determine the optimal amount of water before production and construction can begin.

  1. Refractory powder

Refractory castables are generally mixed with appropriate refractory powder. Its functions: (1) Reduce cement consumption, reduce costs and increase operating temperature. (2) Refractory powder can play a role in infertility, and can participate in reactions at high temperatures to form high-temperature resistant minerals to improve refractory performance. (3) The addition of refractory oxide ultrafine powder can reduce the amount of water, form high-temperature resistant minerals at high temperatures or enhance sintering properties, so it can improve the performance of castables. The type, fineness and dosage of refractory powder are important factors affecting the performance of castables.

The fineness of refractory powder directly affects the strength, bulk density and apparent porosity of refractory castables. Generally speaking, the finer the refractory powder, the better the performance of the refractory castable. When ultrafine powder is used to replace part of the refractory powder, its bulk density increases, its apparent porosity is low, and its strength is significantly improved.

  1. Refractory Aggregate

Refractory aggregate is one of the important components of refractory castables. Its variety, grade, maximum particle size and particle grading are the main factors affecting performance. The influence of refractory aggregate variety on the performance of refractory castables. In addition, the grade, impurity content and sintering quality of refractory aggregate also affect its performance. For example, when alumina clinker is used as refractory aggregate, as the Al2O3 content increases, that is, the grade improves, the refractoriness and load softening temperature of the castable increase, and the linear change after burning decreases. When the material is under-burned or has a high impurity content, its refractoriness and load softening temperature decrease, and the linear shrinkage after burning is large. Therefore, only by selecting suitable refractory aggregates with good sintering and high purity can high-performance refractory castables be prepared.

The more irregular the shape of the refractory aggregate particles, the better, and try not to use long flake materials. Its maximum particle size should be determined according to the thickness of the lining. Once the maximum particle size of the refractory aggregate is determined, its particle grading has a significant impact on the performance of the refractory castable.

  1. Additives

Common additives used in refractory castables are generally divided into water reducers, setting accelerators and setting retarders. In addition, sintering agents and expansion agents are also added. It should be noted that the refractory cement used in refractory castables is different, and the selected additives and their dosage are also different, which should generally be determined by experiment.

  1. Maintenance system

Maintenance systems are divided into standard maintenance, natural maintenance, wet maintenance, steam maintenance, water maintenance and dry maintenance.

The technical team of Rongsheng manufacturer reminds that when constructing amorphous refractory castables, they must be constructed strictly in accordance with the construction instructions. Strictly control the amount of water added. Choose experienced construction workers. To ensure the efficient construction quality. If there are any problems with the construction of refractory castables, technical formula adjustment, etc., please let us know. We can customize refractory lining material solutions according to your actual working conditions.

Acid-Resistant Bricks and Refractory Castables for Chimney Masonry

When buying refractory materials for chimney masonry, is it better to choose acid-resistant bricks or acid-resistant castables? If the purchaser does not have a very clear demand, they will generally wander between the two. Chimney acid-resistant bricks belong to shaped refractory materials, refractory bricks. It has good acid resistance and flue gas erosion resistance. Its structure is compact, the surface is smooth and clean, and it has excellent acid resistance. However, it is brittle, poor in impact resistance, low thermal stability, and easy to crack when exposed to sudden cold and sudden heat. Some manufacturers of refractory materials have made a summary of the refractory materials for chimneys, which are rough as follows.

Acid Proof Bricks For Sale
Acid Proof Bricks For Sale

Question: Is it better to use acid-resistant bricks or acid-resistant castables for chimney masonry?

Which is better for the boiler chimney castable or acid-resistant brick? Castables and acid-resistant bricks have their own advantages. The refractory manufacturer recommends that you read the following in detail so that you can clearly know what kind of product is more suitable for the boiler chimney. Is it better to use castables for boiler chimneys or acid-resistant bricks?

The choice of chimney lining has an important influence on the construction conditions of the chimney. For example, the construction period, local environment, and other conditions affect the choice of lining materials. How to complete the project within the specified construction period? This needs to choose the lining material according to the local environment, temperature, construction conditions, and economy.

Generally speaking, when the height of the chimney is higher than 100 meters, acid-resistant castable is used as the lining, and when the height of the chimney is lower than 100 meters, the acid-resistant brick is used as the lining. No matter what kind of lining, the cylinder construction adopts a single slip form scheme, with an average of 2~3m/d and the slip form is completed in 60 days. After the cylinder sliding form is completed, the lining masonry will not affect the construction of surrounding buildings. Acid-resistant bricks are more complex than acid-resistant castables, so there will be no material returning to alkali after masonry.

When using acid-resistant castables, the castable must be baked in time to drain the free water in the castable. Before the alkali metal and alkaline earth metal substances are converted into hydroxides and migrate, they will react with each other to form stable compounds, thereby preventing the phenomenon of back alkali.

Acid proof brick
Acid-Resistant Bricks for Chimney Masonry

Choose castable or acid-resistant brick for the lining of the boiler chimney?

The traditional chimney project is lined with acid-resistant bricks. In order to reduce the cost and investment, the project plans to use refractory castables as the lining. Refractory castables are characterized by their low bulk density (1/3 of acid-resistant bricks), reducing the amount of chimney wall concrete and foundation steel bars, and low thermal conductivity (castables are 0112W/m·k, acid-resistant bricks are 019W/m·k). There is no need to add a heat insulation layer, which is more economical in design than acid-resistant bricks. Moreover, the performance of the castable is similar to that of the concrete. By combining the embedded steel bar and the concrete, the overall force performance is better. Compared with the economic investment of acid-resistant bricks and refractory castables, the price of refractory castables can save tens of thousands to hundreds of thousands based on the price of acid-resistant bricks. And the running time is long, so it is recommended to use boiler chimney castable as the lining body.

How to choose the lining of the power station boiler chimney?

As the flue gas discharged from the power station boiler chimney is saturated with water after wet deacidification, the flue gas temperature drops to between 50°C and 70°C, and it also contains a small amount of corrosive media such as sulfuric acid and entrained chloride. Due to the strong permeability of low-concentration sulfuric acid and chloride, the corrosion and damage to the inner wall of concrete are stronger than that of high-concentration sulfuric acid solution. Therefore, higher requirements are put forward for the anti-corrosion performance of the chimney lining after wet flue gas desulfurization in coal-fired power plants. The castable for the boiler chimney of the power plant produced by the Rongsheng refractory material manufacturer can be directly poured into the inner layer of the chimney to play a role in heat preservation, heat insulation, acid resistance, and corrosion resistance. And it has the advantages of relatively high compressive strength, which replaces the original traditional light bricks and acid-resistant bricks, and is convenient for construction.

Acid proof brick
Rongsheng Acid Proof Brick Manufacturer

Construction plan for stacking chimney with chimney lined with acid-resistant bricks

The construction plan for stacking chimneys with acid-resistant bricks lining the chimney introduced by the acid-resistant brick manufacturer, I hope will help the one which is looking for the solutions for the construction for the chimney’s lining masonry.

First, clean the inner wall of the chimney with a high-pressure water gun. If the old chimney has been preserved before, the damaged area needs to be cleaned up, and the intact part only needs to be cleaned. Then use special acid-resistant cement to make putty and repair the surface until the application is smooth and smooth. Then the surface of the acid-resistant clay is completely and thoroughly treated with corrosion protection. Using the traditional hoop bucket principle, the hoop ceramic lining with a thickness of 5mm is made outside the anti-corrosion layer, and the ceramic hoop ceramic lining is filled with low-temperature enamel and the surface is enameled.

According to this method, the ceramic-lined chimney is made of a chimney lining with acid-resistant bricks. The inner wall is smooth and beautiful, with four layers of anti-corrosion and excellent corrosion resistance. This should be the first choice for chimney corrosion protection in power generation companies.